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Electrochemical studies of mild steel corrosion inhibition in sulfuric acid chloride by aniline

Loto, R. T. and Loto, C. A. and Fedotova, T. (2013) Electrochemical studies of mild steel corrosion inhibition in sulfuric acid chloride by aniline. Res Chem Intermed.

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Abstract

The corrosion behavior of mild steel in dilute hydrochloric acid under the inhibiting action of various concentrations of aniline was studied using the weight loss and linear polarization resistance technique. The efficiency of the inhibitor increased with the increase in the inhibitor concentration. The results obtained reveal that aniline performed effectively as a corrosion inhibitor. The adsorption mechanism indicates mixed molecular interaction from values of Gibbs free energy. The values of the inhibition efficiency calculated from the two tech- niques are in reasonably good agreement. The adsorption of the inhibiting com- pound was found to obey Langmuir, Frumkin and Freudlich adsorption isotherms. The mechanism of inhibition was discussed in the light of the chemical structure of the inhibiting compound and their adsorption on steel surfaces in relation to the potentiodynamic parameters.

Item Type: Article
Subjects: T Technology > TP Chemical technology
Divisions: Faculty of Engineering, Science and Mathematics > School of Engineering Sciences
Depositing User: Mr Adewole Adewumi
Date Deposited: 21 Aug 2013 18:13
Last Modified: 21 Aug 2013 18:13
URI: http://eprints.covenantuniversity.edu.ng/id/eprint/1356

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