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Synthesis and Characterization of Optically Active Fractal Seed Mediated Silver Nickel Bimetallic Nanoparticles

Dare, Enock Olugbenga and Adekoya, J. A. and Mesubi, M. A. and Revaprasadu, Neerish (2014) Synthesis and Characterization of Optically Active Fractal Seed Mediated Silver Nickel Bimetallic Nanoparticles. Journal of Materials, 2014 (184216).

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Abstract

The synthesis of new seed mediated AgNi allied bimetallic nanocomposites was successfully carried out by the successive reduction of the metal ions in diethylene glycol, ethylene glycol, glycerol, and pentaerythritol solutions, with concomitant precipitation of Ag/Ni bimetal sols. The optical measurement revealed the existence of distinct band edge with surface plasmon resonance(SPR) in the region of 400–425 nm and excitonic emission with maximum peak at 382nm which were reminiscent of clusterin- cluster surface enriched bimetallic silver-nickel sols. The morphological characterization by transmission electron microscopy, high resolution transmission electron microscopy, and X-ray diffraction analyses complimented by surface scan using X-ray photoelectron spectroscopy strongly supported the formation of intimately alloyed face-centered silver/nickel nanoclusters.

Item Type: Article
Subjects: Q Science > QD Chemistry
Divisions: Faculty of Engineering, Science and Mathematics > School of Chemistry
Depositing User: Dr Joseph Adeyemi Adekoya
Date Deposited: 09 Apr 2015 11:10
Last Modified: 09 Oct 2015 11:01
URI: http://eprints.covenantuniversity.edu.ng/id/eprint/4733

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