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EPR and Magnetic Studies on y:bis(N -Methyl Salicylaldimine) Copper(II)

De, Dilip Kumar and GHOSHAL, A. K. and PAL, D. and PAL, A. K. (1981) EPR and Magnetic Studies on y:bis(N -Methyl Salicylaldimine) Copper(II). Depa1·tment of Physics, University of Texas at Arlington1 ) (a) and Indian Association for the Cultivation of Science, Calcutta2 } (b). pp. 645-652.

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EPR and magnetic studies on single crystals of the dimeric copper (II) compound y: his (N-methyl salicylaldimine) Cu(II) down to 1.5 K reveal that each Cu(II) dimer is ferromagnetically exchange coupled having negligible interdimer exchange interaction. The magnetic properties are best described with C4v ligand field symmetry around each Cu(II) ion. The principal axes of the susceptibility and the g-tensor are not strictly coincident at low temperature. EPR und magnetische Untersuchungen an Einkristallen der dimeren Kupfer (II)-Verbindung y: bis-(N-methylsalizylaldimin)- Cu(II) his herab zu 1,5 K zeigen, daB jedes Cu(II)-Dimer ferromagnetisch austauschgekoppelt ist und eine vernachlassigbare interdimere Austauschwechselwirkung aufweist. Die magnetischen Eigenschaften lassen sich am besten mit C4v-Ligandensymmetrie urn jedes Cu(II)-Ion beschreiben. Die Hauptachsen des Suszeptibilitats- und g-Tensoren sind nicht genau koinzident bei tiefen Temperaturen

Item Type: Article
Subjects: Q Science > QH Natural history > QH301 Biology
Divisions: Faculty of Medicine, Health and Life Sciences > School of Biological Sciences
Depositing User: Mrs Patricia Nwokealisi
Date Deposited: 24 Apr 2015 20:25
Last Modified: 24 Apr 2015 20:25

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