Mordi, Raphael C. and Bamgboye, O. A. and Inegbenebor, A. I. (2016) HOFMANN-MARTIUS REARRANGEMENT REACTIONS CATALYSED BY ZEOLITE. In: Covenant University Chemistry Workshop/Conference.
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Abstract
N-Methylaniline was reacted over HZSM-5, H-Theta-1 and HY zeolites and was found to rearrange to give the toluidines, aniline and N,N-dimethylaniline. Percentage conversion to these products was found to be highest over HY zeolite with a higher selectivity to p-toluidine, whereas over HZSM-5 and H-Theta-1 selectivity was to N,N-dimethylaniline. The conversion to these products is in line with Hofmann-Martius and the Reilly-Hickin bottom rearrangement reactions. However the selectivity to N,N-dimethylaniline as observed over HZSM-5 and H-Theta-1 (medium pore zeolites) is new
| Item Type: | Conference or Workshop Item (Paper) |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Engineering, Science and Mathematics > School of Chemistry |
| Depositing User: | Mrs Hannah Akinwumi |
| Date Deposited: | 26 Aug 2016 10:21 |
| Last Modified: | 26 Aug 2016 10:21 |
| URI: | http://eprints.covenantuniversity.edu.ng/id/eprint/6964 |
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