%R https://doi.org/10.1039/C9RA10675H
%P 8558-8567
%A Jindong Wang
%A Wenzhi Li
%A Huizhen Wang
%A Ajibola T Ogunbiyi
%A Xiaomeng Dou
%A Qiaozhi Ma
%T Effects of the novel catalyst Ni–S2O82−–K2O/TiO2 on efficient lignin
depolymerization
%D 2020
%L eprints17379
%X To improve the utilization of lignin, much effort has been devoted to lignin depolymerization
with the aim to decrease waste and enhance profitability. Here, a dual property (acid and
base) catalyst, namely S2O8
2−–K2O/TiO2, was carefully researched. Upon loading S2O8
2− and
K2O onto TiO2, acid and base sites emerged, and S2O8
2− and K2O mutually enhanced the acid
and base strengths of the catalyst enormously; this indeed facilitated lignin depolymerization.
Under appropriate conditions, the yields of liquid product, petroleum ether soluble (PEsoluble)
product and total monomer products were 83.76%, 50.4% and 28.96%, respectively.
The constituents of the PE-soluble fraction, which are mainly monomers and dimers, can be
used as liquid fuels or additives. In addition, after the catalyst was modified by Ni, better
results were obtained. Surprisingly, it was found that the Ni enhanced not only the
hydrogenation capacity but also the acidity. The highest high heating value (HHV) of the
liquid product (33.6 MJ kg−1) was obtained, and the yield of PE-soluble product increased
from 50.4 to 56.4%. The product can be utilized as a fuel additive or be converted to bio-fuel.
This catalysis system has significant potential in the conversion of lignin to bio-fuel.
%N 14
%V 10
%J The Royal Society of Chemistry