James, O. O. and Ajanaku, K. O. and Ajani, Olayinka O. and Siyanbola, T. O. (2010) Towards the conversion of carbohydrate biomass feedstocks to biofuels via hydroxylmethylfurfural. Energy & Environmental Science, 3.
Full text not available from this repository.Abstract
This review appraises the chemical conversion processes recently reported for the production of hydroxylmethylfurfural (HMF), a key biorefining intermediate, from carbohydrate biomass feedstocks. Catalytic sites or groups required for the efficient and selective conversion of hexose substrates to HMF are examined. The principle of concerted catalysis was used to rationalise the dehydration of fructose and glucose to HMF in non-aqueous media. A survey of reported reaction routes to diesel-range biofuel intermediates from HMF or furfural is presented and self-condensation reaction routes for linking two or more HMF and furfural units together toward obtaining kerosene and diesel-range biofuel intermediates are highlighted. The reaction routes include: benzoin condensation, condensation of furfuryl alcohols, hetero Diels–Alder reaction and ketonisation reaction. These reaction routes are yet to be exploited despite their potential for obtaining kerosene and diesel-range biofuel intermediates exclusively from furfural or hydroxylmethylfurfural.
| Item Type: | Article |
|---|---|
| Subjects: | Q Science > QD Chemistry |
| Divisions: | Faculty of Engineering, Science and Mathematics > School of Chemistry |
| Depositing User: | Dr Tolutope Siyanbola |
| Date Deposited: | 25 Feb 2016 12:04 |
| Last Modified: | 25 Feb 2016 12:04 |
| URI: | http://eprints.covenantuniversity.edu.ng/id/eprint/6069 |
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