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Biochemical Characterisation of the Leaf of Morinda Lucida: Prospects for Environmentally-Friendly Steel-Rebar Corrosion-Protection in Aggressive Medium

Okeniyi, Joshua Olusegun and Ogunlana, Olubanke Olujoke and Ogunlana, Oluseyi Ebenezer and Owoeye, Taiwo Felicia and Okeniyi, Elizabeth Toyin (2015) Biochemical Characterisation of the Leaf of Morinda Lucida: Prospects for Environmentally-Friendly Steel-Rebar Corrosion-Protection in Aggressive Medium. In: TMS2015 Supplemental Proceedings. John Wiley & Sons, Inc.,, Hoboken, New Jersey, USA, pp. 635-644. ISBN 9781119082415

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Abstract

This paper employs atomic absorption spectroscopy (AAS), Fourier transform infrared spectroscopy (FTIR) and phytochemical screening methods for biochemical characterisation of the inorganic and organic constituents of the leaf of Morinda lucida. AAS results showed that this well-known medicinal-plant is high in iron (Fe = 5143.54 μg/g), low in cadmium (Cd = 2.9506 μg/g) and does not contain chromium (Cr). Also, Euclidean hit-list from the FT-IR instrument suggests Morinda lucida leaf-extract contains S¬–, N–, Br– and O– containing hetero-atoms. The phytochemical analyses indicated presence of tannins, phlobatannins, saponins, flavonoids and terpenoids. These results bare prospects on suitability of leaf-extract from Morinda lucida for environmentally-friendly steel-rebar corrosion-protection in aggressive medium. Preliminary tests based on this showed that use of 0.083 wt% cement of Morinda lucida retarded steel-rebar total-corrosion and eventually reduced corrosion rate as admixture in duplicated 3.5% NaCl-immersed concretes, relative to control samples in the same medium.

Item Type: Book Section
Uncontrolled Keywords: Morinda lucida; atomic absorption spectroscopy; Fourier transform infrared spectroscopy; phytochemical analyses; steel-rebar corrosion-protection; eco-friendly inhibitor
Subjects: Q Science > Q Science (General)
Q Science > QA Mathematics
Q Science > QC Physics
Q Science > QD Chemistry
S Agriculture > S Agriculture (General)
T Technology > T Technology (General)
T Technology > TA Engineering (General). Civil engineering (General)
T Technology > TD Environmental technology. Sanitary engineering
T Technology > TH Building construction
T Technology > TJ Mechanical engineering and machinery
Divisions: Faculty of Engineering, Science and Mathematics > School of Chemistry
Faculty of Engineering, Science and Mathematics > School of Civil Engineering and the Environment
Faculty of Engineering, Science and Mathematics > School of Engineering Sciences
Faculty of Engineering, Science and Mathematics > School of Mathematics
Faculty of Engineering, Science and Mathematics > School of Physics
Depositing User: Dr Joshua Olusegun Okeniyi
Date Deposited: 15 Aug 2016 10:04
Last Modified: 15 Aug 2016 10:04
URI: http://eprints.covenantuniversity.edu.ng/id/eprint/6860

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