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Optimization of natural gas treatment for the removal of CO2 and H2S in a novel alkaline-DEA hybrid scrubber

Sanni, Samuel Eshorame and Agboola, Oluranti and Fagbiele, Omololu Oluwatobi and Yusuf, Esther Ojima and Emetere, Moses (2019) Optimization of natural gas treatment for the removal of CO2 and H2S in a novel alkaline-DEA hybrid scrubber. Egyptian Journal of Petroleum.

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Abstract

Contaminated natural gas when carelessly handled, often poses human and equipment related problems ranging from lung and skin infections to corrosion, equipment fouling/failure and reduction in gas quality owing to the presence of acid gases. In this work, four natural gas (NG) samples were treated to remove CO2 and H2S using 10–50% Di-Ethanolamine (DEA) solutions mixed with 5% w/w 0.1 M calcium hydroxide. The treatment process gave increased acid gas removal at increased DEA concentrations. Based on the simulation results, cost effective treatment of the gas samples, require 0.1 M Ca(OH)2 and DEA mixed solutions in the range of 27.4–30%. The optimum mixture concentration for the gas treatment was found to be 30% Ca(OH)2-DEA hybrid solution with feed gas flow rate of 830 kscf/h. In terms of pressure energy consumption, pumping the hybrid mix at 830 kscf/h will save pressure energy as compared to pumping the feed gas at 1024.58 kscf/h since the lower and upper limit feed gas flow rates gave similar results. The optimum pressure for NG treatment was found to be in the range of 2–2.7 bar (2–2.7*105 kgm�1 s�2).Contaminated natural gas when carelessly handled, often poses human and equipment related problems ranging from lung and skin infections to corrosion, equipment fouling/failure and reduction in gas quality owing to the presence of acid gases. In this work, four natural gas (NG) samples were treated to remove CO2 and H2S using 10–50% Di-Ethanolamine (DEA) solutions mixed with 5% w/w 0.1 M calcium hydroxide. The treatment process gave increased acid gas removal at increased DEA concentrations. Based on the simulation results, cost effective treatment of the gas samples, require 0.1 M Ca(OH)2 and DEA mixed solutions in the range of 27.4–30%. The optimum mixture concentration for the gas treatment was found to be 30% Ca(OH)2-DEA hybrid solution with feed gas flow rate of 830 kscf/h. In terms of pressure energy consumption, pumping the hybrid mix at 830 kscf/h will save pressure energy as compared to pumping the feed gas at 1024.58 kscf/h since the lower and upper limit feed gas flow rates gave similar results. The optimum pressure for NG treatment was found to be in the range of 2–2.7 bar (2–2.7*105 kgm�1 s�2).

Item Type: Article
Uncontrolled Keywords: Absorption Acid gas Gas treatment Process optimization Process simulation
Subjects: Q Science > QC Physics
T Technology > TP Chemical technology
Divisions: Faculty of Engineering, Science and Mathematics > School of Engineering Sciences
Faculty of Engineering, Science and Mathematics > School of Physics
Depositing User: Mrs Patricia Nwokealisi
Date Deposited: 24 Feb 2020 07:58
Last Modified: 24 Feb 2020 07:58
URI: http://eprints.covenantuniversity.edu.ng/id/eprint/13127

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